Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation

نویسندگان

چکیده

Abstract Atomically monodispersed heterogeneous catalysts with uniform active sites and high atom utilization efficiency are ideal catalytic materials. Designing such type of catalysts, however, remains a formidable challenge. Herein, using wet-chemical method, we successfully achieved mesoporous graphitic carbon nitride (mpg-C 3 N 4 ) supported dual-atom Pt 2 catalyst, which exhibited excellent performance for the highly selective hydrogenation nitrobenzene to aniline. The conversion ?99% is significantly superior corresponding values mpg-C -supported single atoms ultra-small nanoparticles (~2 nm). First-principles calculations revealed that unique species originates from facile H dissociation induced by diatomic characteristics easy desorption aniline product. produced /mpg-C samples versatile can be applied in catalyzing other important reactions, as benzaldehyde epoxidation styrene.

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ژورنال

عنوان ژورنال: Nature Communications

سال: 2021

ISSN: ['2041-1723']

DOI: https://doi.org/10.1038/s41467-021-23517-x